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Physical Chemistry
List of top Physical Chemistry Questions on Statistical thermodynamics
If the translational partition function for \(\mathrm{H_2}\) confined in a 1 L vessel at 300 K is \(y \times 10^{27}\), then the value of \(y\) is
(rounded off to one decimal place).
(Given: Atomic mass (in amu): H = 1.008; 1 amu = \(1.661 \times 10^{-27}\) kg; \(h = 6.626 \times 10^{-34}\) J s; \(k = 1.381 \times 10^{-23}\) J K\(^{-1}\))
GATE CY - 2026
GATE CY
Physical Chemistry
Statistical thermodynamics
If q
t
and Q
t,m
are the molecular and molar translational partition functions of X
2
, respectively, then In(Q
t,m
) =
(N is the Avogadro number)
GATE CY - 2024
GATE CY
Physical Chemistry
Statistical thermodynamics
The \(\Delta_o\) of [Cr(H\(_2\)O)\(_6\)]\(^3+\), [CrF\(_6\)]\(^3-\), and [Cr(CN)\(_6\)]\(^3-\) follows the order:
GATE CY - 2021
GATE CY
Physical Chemistry
Statistical thermodynamics