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Delhi UMET/DPMT
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Chemistry
List of top Chemistry Questions asked in Delhi UMET/DPMT
A chemical reaction proceeds into the following steps Step I,
$\hspace15mm 2A \rightleftharpoons X$
fast Step II,
$\hspace10mm X + B \rightleftharpoons Y$
slow Step III,
$\hspace10mm Y + B \rightleftharpoons $
Product fast The law for the overall reaction is
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Chemical Kinetics
A solution is
$0.1 M$
with respect to
$Ag ^{+}, Ca ^{2+}, Mg ^{2+}$
and
$Al ^{3+}$
, which will precipitate at lowest concentration of
$\left[ PO _{4}^{3-}\right]$
when solution of
$Na _{3} PO _{4}$
is added?
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Equilibrium
Most stable carbocation is
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Organic Chemistry- Some Basic Principles and Techniques
Given a gas phase reaction,
$\hspace10mm 2A(g)+B(g) \rightleftharpoons C(g)+D(g)$
Which one of the following changes will affect the value of
$K_c$
?
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Equilibrium
The equilibrium constant for mutarotation
$\alpha-D \rightleftharpoons \beta-D$
Glucose is
$1.8$
. What percentage of
$\alpha$
form remains at equilibrium?
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Equilibrium
Number of isomeric forms (constitutional and stereoisomers) for
$ [Rh(en)_{2}(NO_{2})\,(SCN)^{+} $
are
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Isomerism in Coordination Compounds
Maltose gives rise to two molecules of
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Carbohydrates
Identify the reagents
$(X, Y, Z)$
used in the conversion of
$3$
-methylaniline to
$3$
-nitrotoluene.
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Chemical Reactions
The correct decreasing order of dipole moment in $ CH_{3}Cl,\,CH_{3} Br$ and $ CH_{3}F $ is
Delhi UMET/DPMT - 2011
Delhi UMET/DPMT
Chemistry
Polarity of bonds
Which of the following represents the arrangement in increasing order of bond order and bond dissociation energy?
Delhi UMET/DPMT - 2010
Delhi UMET/DPMT
Chemistry
Chemical bonding and molecular structure
For a first order reaction, the time required for $99.9\%$ of the reaction to take place is nearly
Delhi UMET/DPMT - 2009
Delhi UMET/DPMT
Chemistry
Chemical Kinetics
The size of the nucleus of an atom of mass number
$A$
is proportional to
Delhi UMET/DPMT - 2009
Delhi UMET/DPMT
Chemistry
Bohr’s Model for Hydrogen Atom
Which of the following reactions involves carbon-carbon bond formation
Delhi UMET/DPMT - 2009
Delhi UMET/DPMT
Chemistry
Aldehydes, Ketones and Carboxylic Acids
In the change of $NO \, \to\, NO^+$ the electron is added to
Delhi UMET/DPMT - 2009
Delhi UMET/DPMT
Chemistry
Chemical bonding and molecular structure
Chlorobenzene is ...... reactive than benzene towards electrophilic substitution and directs the incoming electrophile to the ...... position.
Delhi UMET/DPMT - 2009
Delhi UMET/DPMT
Chemistry
Chemical Reactions
Which of the following reactions involves carbon-carbon bond formation?
Delhi UMET/DPMT - 2009
Delhi UMET/DPMT
Chemistry
Chemical Reactions
Two ice cubes are pressed over each other until they unite to form one block. Which one of the following forces dominates for holding them together ?
Delhi UMET/DPMT - 2009
Delhi UMET/DPMT
Chemistry
Chemical bonding and molecular structure
Which of the following is chiral?
Delhi UMET/DPMT - 2008
Delhi UMET/DPMT
Chemistry
Isomerism
In the following reaction
$NH _{4}^{+}+ BiN \rightarrow NH _{3}+ Bi ^{3+} NH _{4}^{+}$
is acting as an
Delhi UMET/DPMT - 2008
Delhi UMET/DPMT
Chemistry
Group 15 Elements
The following solids are formed by
$X,\, Q$
and
$Z.\, XY_{2},\,X_{2}Z,\,QZ$
. Then the formula of the compound formed by
$Q$
and
$Y$
is
Delhi UMET/DPMT - 2008
Delhi UMET/DPMT
Chemistry
Properties of Solids
In the following complex compound
$\left[ Co \left( NH _{3}\right)_{4} Cl _{2}\right]^{+}$
, Co and
$Cl$
are collinear. Which of the following structures is possible?
Delhi UMET/DPMT - 2008
Delhi UMET/DPMT
Chemistry
Isomerism in Coordination Compounds
In the given compound which of the following hydrogens is most acidic?
$\underset{(a)}{CH_3} -\underset{(b)}{CH_2} -\overset{\underset{||}{O}}{C} -\underset{(c)}{CH_3}$
Delhi UMET/DPMT - 2008
Delhi UMET/DPMT
Chemistry
Chemical Reactions
Identify
$B$
in the following reaction
Delhi UMET/DPMT - 2008
Delhi UMET/DPMT
Chemistry
Chemical Reactions
Which of the following is not present in a nucleotide?
Delhi UMET/DPMT - 2008
Delhi UMET/DPMT
Chemistry
Biomolecules
$\Psi^{2}=0$
represent
Delhi UMET/DPMT - 2007
Delhi UMET/DPMT
Chemistry
Quantum Mechanical Model of Atom
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