Question:

Which one of the following is an S-containing vitamin?

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Sulfur-Containing Biomolecules:
Sulfur Vitamins = THIAMIN (Thiazole ring) & BIOTIN (Thiophene ring).
Sulfur Amino Acids = Methionine, Cysteine, Cystine.
  • Thiamin
  • Niacin
  • Pyridoxine
  • Folacin
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The Correct Option is A

Solution and Explanation


Step 1: Understanding the Concept:

Chemical structural classification of water-soluble vitamins: thiamin and biotin contain heterocyclic sulfur atoms.
Key Formula or Approach:
\[ \text{Thiamin (Vitamin B}_1\text{)} = \text{Substituted Pyrimidine Ring} + \text{Sulfur-Containing Thiazole Ring} \]

Step 2: Detailed Explanation:

Chemical structures of water-soluble vitamins:
1. Thiamin (Vitamin $\text{B}_1$): Consists of an aminopyrimidine ring connected via a methylene bridge to a sulfur-containing thiazole ring ($-S-$). (Biotin also contains sulfur in a tetrahydrothiophene ring).
2. Niacin: Pyridine ring (contains nitrogen).
3. Pyridoxine: Pyridine derivative.
4. Folacin (Folic acid): Pteridine ring $+$ PABA $+$ Glutamic acid.
Therefore, Thiamin is the sulfur-containing vitamin.

Step 3: Final Answer:

Thus, Thiamin is an S-containing vitamin, matching option (A).
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