Step 1: Concept
Pyrometallurgy involves thermal treatment of minerals (roasting, smelting, calcination).
Step 2: Meaning
Hydrometallurgy involves the use of aqueous solutions to extract metals from ores.
Step 3: Analysis
Calcination, roasting, and smelting use high temperatures. Leaching uses chemical solutions at low temperatures.
Step 4: Conclusion
Leaching is a hydrometallurgical process, not a pyrometallurgical one.
Final Answer: (D)