Concept:
A semiconductor is called electrically negative when electrons are the majority charge carriers.
Such semiconductors are called \(n\)-type semiconductors.
Step 1: Recall the effect of doping.
\[
\begin{aligned}
\text{Pentavalent} &\rightarrow n\text{-type} \rightarrow \text{Electrons} \\
\text{Trivalent} &\rightarrow p\text{-type} \rightarrow \text{Holes}
\end{aligned}
\]
Step 2: Identify the electrically negative semiconductor.
Pentavalent impurities contribute extra electrons.
Hence,
\[
\text{electrons}\gt \text{holes}.
\]
Therefore the semiconductor behaves as an electrically negative semiconductor.
\[\begin{aligned}
\boxed{\text{Silicon doped with pentavalent impurities}}
\end{aligned}\]
Hence, option \(\mathbf{(B)}\) is correct.