Step 1: Understanding the Concept:
Monounsaturated fatty acids (MUFA) are fatty acids that contain exactly one double bond in their carbon chain.
In milk fat and butter, unsaturated fatty acids make up approximately 30% to 35% of the total fatty acid profile, with monounsaturated fatty acids being the largest contributor to this fraction.
Step 2: Detailed Explanation:
Oleic acid ($C18:1$, cis-9-octadecenoic acid) is the primary monounsaturated fatty acid found in butter fat.
It typically accounts for 20% to 30% of the total fatty acid composition in butter, depending on seasonal factors and bovine feed.
Oleic acid plays a major role in determining the melting point, hardness, and spreadability of butter at refrigerated temperatures.
Vaccenic acid is a trans-monounsaturated fatty acid present in much smaller amounts (around 1% to 2%) as a natural byproduct of rumen biohydrogenation.
Elaidic acid is the trans-isomer of oleic acid, which is not highly abundant in natural milk fat.
Marvalic acid is not a standard major monounsaturated fatty acid in dairy products.
Therefore, oleic acid is the principal MUFA present in butter.
Step 3: Final Answer
The correct option is (D).