Concept: Local anesthetics are split into two families based on the linking group in the middle of the molecule: ester-type and amide-type. A simple memory trick is that amide-type drugs usually have two letter "i"s in their name.
Step 1: Procaine, Benzocaine and Tetracaine all contain an ester linkage, so they are ester-type local anesthetics.
Step 2: Lidocaine contains an amide linkage in its structure, which makes it the amide-type local anesthetic. (Notice it has two "i"s: L-i-doca-i-ne.)