The initial car requires 6 hours to reach the destination.
While the second car, starting an hour later, accomplishes the journey in 5 hours, reaching at the same time.
In cases of constant distance, the ratio between speed and time reverse.
The percentage by which the speed of the second car could surpass that of the first car is calculated :
= 1/5 × 100, resulting in 20%.
Hence, the maximum potential percentage by which the speed of the second car could exceed that of the first car is 20%.