Question:

The second law of thermodynamics states that:

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Logic Tip: The First Law says you can't get something for nothing (Energy is conserved). The Second Law says you can't even break even (Entropy/disorder always increases in the universe).
  • Energy is always conserved
  • Heat can be completely converted into work
  • Entropy of an isolated system always increases
  • Pressure is proportional to temperature
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The Correct Option is C

Solution and Explanation

Concept:
The Second Law of Thermodynamics governs the directionality of processes and the concept of irreversibility, introducing the property of entropy ($S$).

Step 1:
This describes the First Law of Thermodynamics, not the Second.

Step 2:
The Kelvin-Planck statement of the Second Law explicitly declares it is impossible to construct an engine that completely converts all absorbed heat into work; some waste heat must always be rejected.

Step 3:
This relationship relates to ideal gas laws (Gay-Lussac's law), not the fundamental laws of macroscopic thermodynamics.

Step 4:
The principle of increase of entropy states that for any spontaneous, real-world process occurring in an isolated system, the total entropy (disorder) must always increase.
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