Step 1: Understanding the Concept:
Soil colloids are categorized into organic (humus) and inorganic (layer silicate clays and hydrous iron/aluminum oxides) fractions, which are either crystalline or amorphous.
Step 2: Detailed Explanation:
1. Smectite (Montmorillonite group): An inorganic 2:1 phyllosilicate layer clay mineral possessing a well-defined, repeating crystalline lattice structure of silicon-oxygen tetrahedra and aluminum-oxygen octahedra.
2. Allophane and Imogolite: Inorganic amorphous (non-crystalline) colloids.
3. Humus: Organic amorphous colloid.
Therefore, smectite is an Inorganic crystalline colloid.
Step 3: Final Answer:
Hence, smectite mineral colloid is an Inorganic crystalline colloid, corresponding to option (B).