Step 1: Understanding the Concept:
Wastewater treatment trains are systematically organized into primary (physical/chemical), secondary (biological), and tertiary (advanced polishing) stages.
Step 2: Detailed Explanation:
Primary wastewater treatment focuses on removing settleable solids and suspended colloidal matter.
The addition of chemical coagulants like alum (aluminum sulfate, $\text{Al}_2(\text{SO}_4)_3$) neutralizes surface charges of suspended colloids, promoting flocculation and rapid sedimentation in primary settling tanks (chemically enhanced primary treatment).
Secondary treatment uses biological microbial digestion (activated sludge/trickling filters), and tertiary treatment involves advanced disinfection/filtration.
Step 3: Final Answer:
Therefore, coagulation/flocculation with alum is termed primary treatment.