Step 1: Understanding the Concept:
Pectic polysaccharides undergo sequential enzymatic modifications during fruit development, ripening, and senescence.
Step 2: Detailed Explanation:
The maturation pathway of pectic substances proceeds as follows:
1. Unripe fruit: Water-insoluble protopectin predominates, conferring rigid firmness.
2. Ripe fruit: Protopectin is hydrolyzed into water-soluble pectin (pectinic acid, methylated polygalacturonan) which possesses jelly-forming ability.
3. Over-ripe fruit: Pectinesterase and polygalacturonase de-esterify and hydrolyze pectin into completely demethylated pectic acid, which cannot form gels and results in tissue softening.
Step 3: Final Answer:
Hence, in over-ripe fruit, pectin is converted into pectic acid.