A parallel plate capacitor is charged by an AC source. Show that the sum of conduction current \( I_c \) and displacement current \( I_d \) has the same value at all points in the circuit.
In an AC circuit, the current \( I_c \) continuously changes direction. Charges accumulate and deplete on the capacitor plates, creating a time-varying electric field between them. This changing field gives rise to a displacement current \( I_d \) in the dielectric.
Maxwell showed that:
\( I_c = I_d \)
This equality ensures that the current appears continuous throughout the entire circuit, including the space between the capacitor plates where no actual charge carriers move.
Yes, Kirchhoff’s first law (junction rule) is valid at each plate of the capacitor, because the sum of the conduction current \( I_c \) and the displacement current \( I_d \) is the same at all points in the circuit.
Reason: The displacement current ensures there is no accumulation of charge at any point in the circuit. Therefore, current continuity is maintained, and the junction rule:
\( \sum I_{\text{in}} = \sum I_{\text{out}} \)
holds true even at the surfaces of the capacitor plates.
The concept of displacement current bridges the gap in the dielectric region of a capacitor, thereby upholding Kirchhoff’s current law universally, even in time-varying (AC) circuits.
(a) Calculate the standard Gibbs energy (\(\Delta G^\circ\)) of the following reaction at 25°C:
\(\text{Au(s) + Ca\(^{2+}\)(1M) $\rightarrow$ Au\(^{3+}\)(1M) + Ca(s)} \)
\(\text{E\(^\circ_{\text{Au}^{3+}/\text{Au}} = +1.5 V, E\)\(^\circ_{\text{Ca}^{2+}/\text{Ca}} = -2.87 V\)}\)
\(\text{1 F} = 96500 C mol^{-1}\)
Define the following:
(i) Cell potential
(ii) Fuel Cell
Calculate the emf of the following cell at 25°C:
\[ \text{Zn(s)} | \text{Zn}^{2+}(0.1M) || \text{Cd}^{2+}(0.01M) | \text{Cd(s)} \] Given: \[ E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.40 \, V, \, E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, V \] \[ [\log 10 = 1] \]
Write chemical equations of the following reactions:
(i) Phenol is treated with conc. HNO\(_3\)
(ii) Propene is treated with B\(_2\)H\(_6\) followed by oxidation by H\(_2\)O\(_2\)/OH\(^-\)
(iii) Sodium t-butoxide is treated with CH\(_3\)Cl
Give a simple chemical test to distinguish between butan-1-ol and butan-2-ol.