Given integral:
\[ \int_{0}^{\frac{\pi}{4}} \frac{\sin^2 x}{1 + \sin x \cos x} dx = \int_{0}^{\frac{\pi}{4}} \frac{\sin^2 x}{1 + \frac{1}{2} \sin 2x} dx = \int_{0}^{\frac{\pi}{4}} \frac{1 - \cos 2x}{2 + \sin 2x} dx \]
We separate this into two integrals:
\[ \int_{0}^{\frac{\pi}{4}} \frac{1}{2 + \sin 2x} dx - \int_{0}^{\frac{\pi}{4}} \frac{\cos 2x}{2 + \sin 2x} dx \]
Denote these integrals as \(I_1\) and \(I_2\) respectively:
\[ I_1 = \int_{0}^{\frac{\pi}{4}} \frac{dx}{2 + \sin 2x}, \quad I_2 = \int_{0}^{\frac{\pi}{4}} \frac{\cos 2x}{2 + \sin 2x} dx \]
For \(I_1\), let \(\tan x = t\), hence:
\[ dx = \frac{dt}{1 + t^2}, \quad \sin 2x = \frac{2t}{1 + t^2} \]
Substituting these into the integral:
\[ I_1 = \frac{1}{2} \int_{0}^{1} \frac{dt}{\left(t + \frac{1}{2}\right)^2 + \left(\frac{\sqrt{3}}{2}\right)^2} = \frac{\pi}{6\sqrt{3}} \]
For \(I_2\), we use:
\[ I_2 = \int_{0}^{\frac{\pi}{4}} \frac{\cos 2x}{2 + \sin 2x} dx \]
Applying another substitution and evaluating, we find:
\[ I_2 = \frac{1}{2} \ln \left(\frac{3}{2}\right) \]
Thus, the original integral becomes:
\[ I = I_1 - I_2 = \frac{\pi}{6\sqrt{3}} - \frac{1}{2} \ln \left(\frac{3}{2}\right) \]
Given that:
\[ \int_{0}^{\frac{\pi}{4}} \frac{\sin^2 x}{1 + \sin x \cos x} dx = \frac{1}{a} \ln_e \left(\frac{a}{3}\right) + \frac{\pi}{b\sqrt{3}} \]
Comparing terms, we find: \[ a = 2, \quad b = 6 \]
Therefore:
\[ a + b = 2 + 6 = 8 \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,