Which of the following best represents the temperature versus heat supplied graph for water, in the range of \(-20^\circ\text{C}\) to \(120^\circ\text{C}\)? 
In the following \(p\text{–}V\) diagram, the equation of state along the curved path is given by \[ (V-2)^2 = 4ap, \] where \(a\) is a constant. The total work done in the closed path is: 
Given below are two statements:
Statement I: Benzene is nitrated to give nitrobenzene, which on further treatment with \( \text{CH}_3\text{COCl} / \text{AlCl}_3 \) will give the product shown. 
Statement II: \( -\text{NO}_2 \) group is a meta-directing and deactivating group.
In the light of the above statements, choose the most appropriate answer from the options given below.