Solution:
Let the coefficient matrix be
\[
A = \begin{vmatrix} 2 & 4 & 2a \\ 1 & 2 & 3 \\ 2 & -5 & 2 \end{vmatrix}, \quad \Delta = \det(A).
\]
Expanding:
\[
\Delta = 2\begin{vmatrix} 2 & 3 \\ -5 & 2 \end{vmatrix} - 4\begin{vmatrix} 1 & 3 \\ 2 & 2 \end{vmatrix} + 2a\begin{vmatrix} 1 & 2 \\ 2 & -5 \end{vmatrix}.
\]
Evaluating each minor:
\[
\begin{vmatrix} 2 & 3 \\ -5 & 2 \end{vmatrix} = 4 + 15 = 19, \quad \begin{vmatrix} 1 & 3 \\ 2 & 2 \end{vmatrix} = 1 \cdot 2 - 3 \cdot 2 = 2 - 6 = -4, \quad \begin{vmatrix} 1 & 2 \\ 2 & -5 \end{vmatrix} = (1)(-5) - (2)(2) = -5 - 4 = -9.
\]
So
\[
\Delta = 2 \cdot 19 - 4 \cdot (-4) + 2a \cdot (-9) = 38 + 16 - 18a = 54 - 18a = 18(3 - a).
\]
For a unique solution, we need \(\Delta \neq 0\), hence \(a \neq 3\).
To determine if the system has infinitely many solutions, we require \(\Delta = 0\) (\(a = 3\)), and also the system must be consistent in its rank conditions. Substituting \(a = 3\) into the equations and analyzing the augmented matrix can lead to constraints on \(b\). One finds that if \(a = 3\) and \(b = 8\), the system has infinitely many solutions (making (1) true).
Checking the other claims shows that (2) and (3) are correct for unique solutions under those specific parameter choices. However, for (4) \(a = 3, b = 6\), it does not provide infinitely many solutions (the system fails to have infinitely many solutions with those values).
Hence, statement (4) is not correct.
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,