Step 1: Understanding the Concept:
Slow-release fertilizers are synthesized to have low water solubility, allowing them to release plant-available nutrients over an extended period through chemical or microbial breakdown.
Step 2: Detailed Explanation:
- Urea-formaldehyde (UF) (A): A condensation product of urea and formaldehyde. It is a classic slow-release fertilizer that relies on soil microbes to mineralize and release nitrogen.
- Phenyl phosphorodiamidate (PPDA) (B): Is a urease inhibitor, not a slow-release fertilizer. It functions by temporarily blocking the urease enzyme to reduce ammonia volatilization losses from urea.
- Urea-Z (C): A specialized urea-acetaldehyde condensation compound designed as a slow-release nitrogen source.
- Crotonylidene diurea (CDU) (D): A slow-release nitrogen fertilizer formed by the reaction of urea with crotonaldehyde, which undergoes gradual chemical hydrolysis and microbial degradation in soil.
- Therefore, (A), (C), and (D) are slow-release fertilizers, while (B) is a metabolic inhibitor.
Step 3: Final Answer:
The slow-release fertilizers in the list are (A), (C) and (D) only.