Question:

First unit operation in oil refining process is

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Refining sequence: Degumming $\rightarrow$ Alkali Neutralization $\rightarrow$ Bleaching $\rightarrow$ Winterization $\rightarrow$ Deodorization.
  • Blanching
  • Winterization
  • Deodorization
  • Alkali treatment
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The Correct Option is D

Solution and Explanation


Step 1: Understanding the Concept:

Chemical refining of crude vegetable oils involves sequential purification operations to remove phospholipids, free fatty acids (FFA), pigments, waxes, and volatile odorants.

Step 2: Detailed Explanation:

The standard sequence of unit operations in edible oil chemical refining is:
1. Degumming: Removal of hydratable phospholipids.
2. Alkali Refining Neutralization (Alkali treatment): Addition of sodium hydroxide (NaOH) solution to convert free fatty acids into insoluble soapstock.
3. Bleaching: Adsorption of pigments using activated bleaching clay.
4. Winterization Dewaxing: Crystallization and filtration of high-melting waxes.
5. Deodorization: High-temperature steam vacuum distillation to remove volatile odoriferous compounds.
Among the listed options, Alkali treatment is the first primary chemical refining operation.

Step 3: Final Answer:

Therefore, the first unit operation among the options is Alkali treatment, corresponding to option (D).
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