Step 1: Analyzing (S1).
Consider the equation \( \frac{z - i}{z + i} \) being purely real.
This means the imaginary part of \( \frac{z - i}{z + i} \) must be zero.
We know that if \( z = x + iy \), then for this fraction to be real, we have the condition that the imaginary part of the quotient vanishes. Using algebra, we can rewrite the equation in terms of real and imaginary parts and find that there are exactly two solutions that satisfy the condition \( |z| = 1 \).
Hence, \( \{ z \in \mathbb{C} - \{-i\} : |z| = 1 \text{ and } \frac{z - i}{z + i} \text{ is purely real} \} \) contains exactly two elements, so statement (S1) is correct.
Step 2: Analyzing (S2).
Consider the equation \( \frac{z - 1}{z + 1} \) being purely imaginary.
This means the real part of \( \frac{z - 1}{z + 1} \) must be zero. Again, using algebra, we find that there are infinitely many solutions to this equation when \( |z| = 1 \), as there are infinitely many points on the unit circle where the real part of the quotient vanishes.
Therefore, statement (S2) is also correct.
Step 3: Conclusion.
Thus, the correct answer is: \[ \text{Only (S2) is correct}. \]
Given: \[ S_1 : |z| = 1, \quad \frac{z - i}{z + i} = \frac{\bar{z} + i}{\bar{z} - i} \] \[ \Rightarrow (z - i)(\bar{z} - i) = (z + i)(\bar{z} + i) \] \[ |z|^2 - i(z + \bar{z}) - 1 = |z|^2 + i(z + \bar{z}) - 1 \] \[ i(z + \bar{z}) = 0 \] \[ z + \bar{z} = 2\cos\theta = 0 \Rightarrow \cos\theta = 0 \] \[ z = 0 + 0i, \quad |z| \ne 1 \] Now consider: \[ S_1 : \frac{z - 1}{z + 1} + \frac{\bar{z} - 1}{\bar{z} + 1} = 0 \] \[ (z - 1)(\bar{z} + 1) + (z + 1)(\bar{z} - 1) = 0 \] \[ \Rightarrow |z|^2 + (z - \bar{z}) - 1 + |z|^2 + (\bar{z} - z) - 1 = 0 \] \[ \Rightarrow 2|z|^2 - 2 = 0 \] \[ \boxed{|z|^2 = 1} \]

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,