
Which of the following best represents the temperature versus heat supplied graph for water, in the range of \(-20^\circ\text{C}\) to \(120^\circ\text{C}\)? 
A flexible chain of mass $m$ is hanging as shown. Find tension at the lowest point. 

The temperature at which the rate constants of the given below two gaseous reactions become equal is ____________ K (Nearest integer).
\[ X \longrightarrow Y, \qquad k_1 = 10^{6} e^{-\frac{30000}{T}} \] \[ P \longrightarrow Q, \qquad k_2 = 10^{4} e^{-\frac{24000}{T}} \] Given: \( \ln 10 = 2.303 \)