A bead of mass \( m \) slides without friction on the wall of a vertical circular hoop of radius \( R \) as shown in figure. The bead moves under the combined action of gravity and a massless spring \( k \) attached to the bottom of the hoop. The equilibrium length of the spring is \( R \). If the bead is released from the top of the hoop with (negligible) zero initial speed, the velocity of the bead, when the length of spring becomes \( R \), would be (spring constant is \( k \), \( g \) is acceleration due to gravity): 
\[ U_{\text{top}} = mgh = mg(2R) \]
\[ K_{\text{bottom}} = \frac{1}{2} m v^2 \]
\[ U_{\text{spring}} = \frac{1}{2} k R^2 \]
\[ m g (2R) = \frac{1}{2} m v^2 + \frac{1}{2} k R^2 \]
\[ v = \sqrt{\frac{2gR + kR^2}{m}} \]
Which of the following best represents the temperature versus heat supplied graph for water, in the range of \(-20^\circ\text{C}\) to \(120^\circ\text{C}\)? 
A flexible chain of mass $m$ is hanging as shown. Find tension at the lowest point. 

The temperature at which the rate constants of the given below two gaseous reactions become equal is ____________ K (Nearest integer).
\[ X \longrightarrow Y, \qquad k_1 = 10^{6} e^{-\frac{30000}{T}} \] \[ P \longrightarrow Q, \qquad k_2 = 10^{4} e^{-\frac{24000}{T}} \] Given: \( \ln 10 = 2.303 \)